Generation and reaction of an oxiranyl anion derived from α,β-epoxy-γ-butyrolactone

被引：26

作者：

Kuramochi, K ^{[1
]}

Itaya, H ^{[1
]}

Nagata, S ^{[1
]}

Takao, K ^{[1
]}

Kobayashi, S ^{[1
]}

机构：

[1] Sci Univ Tokyo, Fac Pharmaceut Sci, Shinjuku Ku, Tokyo 1620826, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 41期

关键词：

oxiranyl anion; beta-angelica lactone epoxide; fluoride-catalyzed aldol reaction; epolactaene;

D O I：

10.1016/S0040-4039(99)01511-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Generation and reaction of an oxiranyl anion on a lactone are described. Aldol-type condensation of epoxylactone and aldehydes was accomplished by a two-step procedure via trimethylsilyl epoxylactone. (C) 1999 Elsevier Science Ltd. All rights reserved.

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页码：7367 / 7370

页数：4

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