The oxidation of hydrogen cyanide and related chemistry

被引：328

作者：

Dagaut, Philippe ^{[1
]}

Glarborg, Peter ^{[2
]}

Alzueta, Maria U. ^{[3
]}

机构：

[1] CNRS, F-45071 Orleans 2, France

[2] Tech Univ Denmark, Dept Chem Engn, DK-2800 Lyngby, Denmark

[3] Univ Zaragoza, Aragon Inst Engn Res, Dept Chem & Environm Engn, Zaragoza 50018, Spain

来源：

PROGRESS IN ENERGY AND COMBUSTION SCIENCE | 2008年 / 34卷 / 01期

关键词：

hydrogen cyanide; HCN; nitrogen oxide; NOx; pollutants; oxidation; combustion; kinetics; reburning; prompt-NO; fuel-NO; modeling;

D O I：

10.1016/j.pecs.2007.02.004

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

For modeling the formation of nitrogen oxides in combustion via both the prompt-NO and the fuel-NO mechanisms, as well as for modeling the reduction of nitrogen oxides via reburning, a good knowledge of the kinetics of oxidation of hydrogen cyanide (HCN) is required. The formation routes to HCN and the thermochemistry of HCN-related species arc reviewed. The available kinetic data for the oxidation of HCN are presented and a comprehensive detailed chemical kinetic reaction mechanism for the oxidation of HCN is proposed and discussed. (C) 2007 Elsevier Ltd. All rights reserved.

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页码：1 / 46

页数：46

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