Dioxygen complexes from the reactions of [Cp*RuH2(PP)]+ (PP = dppm, dppe) with air

被引：40

作者：

Jia, GC ^{[1
]}

Ng, WS

Chu, HS

Wong, WT

Yu, NT

Williams, ID

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong, Peoples R China

[2] Univ Hong Kong, Hong Kong, Peoples R China

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 18期

关键词：

D O I：

10.1021/om990317b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Exposure of [Cp*RuH2(dppm)]BF4 in acetone or methanol to air produced a mixture of [Cp*Ru(O-2)(dppm)]BF4 and [Cp*Ru(O-2)(Ph2PCH2P(O)Ph-2)]BF4. Reaction of Cp*RuCl(dppm) with NaBPh4 in methanol in air produced the dioxygen complex [Cp*Ru(O-2)(dppm)]BPh4, which has been characterized by X-ray diffraction. Reaction of Cp*RuCl(dppm) with H2O2 in the presence of NaBPh4 in air produced [Cp*Ru(O-2)(Ph2PCH2P(O)Ph-2)]BPh4 and PH2P(O)CH2P(O)PPh2. Reaction of [Cp*RuH2(dppe)]BF4 in acetone or methanol with air also produced a mixture of [Cp*Ru(O-2)(dppe)]BF4 and [Cp*Ru(O-2)(Ph2PCH2CH2P(O)Ph-2)]BF4.

引用

页码：3597 / 3602

页数：6

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