Pyridinium dichromate: A novel reagent for the oxidation of steroidal delta(5)-3 beta-alcohols to the corresponding delta(4)-3,6-diketones

被引：15

作者：

Hector, M ^{[1
]}

Hartmann, RW ^{[1
]}

Njar, VCO ^{[1
]}

机构：

[1] UNIV SAARLAND,FACHRICHTUNG PHARMAZEUT CHEM 121,D-66041 SAARBRUCKEN,GERMANY

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 06期

关键词：

D O I：

10.1080/00397919608003714

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel procedure for the direct conversion of steroidal Delta(5)-3 beta-alcohols to the corresponding Delta(4)-3,6-diketones in high yield (66-85%) has been achieved using pyridinium dichromate (PDC) in dimethylformamide (DMF) at room temperature.

引用

页码：1075 / 1082

页数：8

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