Further evidence for the assignment of the XCN band in astrophysical ice analogs to OCN- -: Spectroscopy and deuterium shift

被引：62

作者：

Novozamsky, JH

Schutte, WA ^{[1
]}

Keane, JV

机构：

[1] Leiden Observ, Raymond & Beverly Sackler Lab Astrophys, NL-2300 RA Leiden, Netherlands

[2] Univ Groningen, Kapteyn Astron Inst, NL-9700 AV Groningen, Netherlands

来源：

ASTRONOMY & ASTROPHYSICS | 2001年 / 379卷 / 02期

关键词：

methods : laboratory; ISM : molecules; infrared : ISM : lines and bands;

D O I：

10.1051/0004-6361:20011332

中图分类号：

P1 [天文学];

学科分类号：

0704 ;

摘要：

The nu (3) feature of the OCN- ion near 2160 cm(-1) which is produced by acid-base reactions in cryogenic HNCO/NH3 samples shows a small matrix induced deuterium shift. A similar shift is found for the "XCN" band near this position produced by photolysis of CO/NH3 ice. This agreement, together with the abundant evidence already in the literature, clearly demonstrates that the XCN feature can be assigned to OCN-.

引用

页码：588 / 591

页数：4

共 26 条

[1] H, C, N, and O isotopic substitution studies of the 2165 wavenumber (4.62 micron) "XCN" feature produced by ultraviolet photolysis of mixed molecular ices [J].