Dipyridylamine-ligated octamolybdate clusters aggregated into extended ribbons and layers via hydrogen bonding

被引：32

作者：

LaDuca, RL

Rarig, RS

Zapf, PJ

Zubieta, J ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

[2] Univ London Kings Coll, Dept Chem & Phys, Wilkes Barre, PA 18711 USA

来源：

INORGANICA CHIMICA ACTA | 1999年 / 292卷 / 01期

基金：

美国国家科学基金会;

关键词：

crystal structures; molybdate complexes; dipyridylamine complexes; cluster complexes;

D O I：

10.1016/S0020-1693(99)00176-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of MoO3 with 4,4'-dipyridylamine yields [Mo8O26(4,4'-dpa)(2)][4,4'-dpaH(2)](2). The structure consists of octamolybdate clusters linked via H-bonding to the (dpaH(2))(2+) cations into one-dimensional ribbons which are in turn connected through H-bonding into two-dimensional sheets. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：131 / 136

页数：6

共 20 条

[1]

BART JCJ, 1979, P CLIM 3 INT C CHEM

[2]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[3]

2-Z

[4]

CREAGH DC, 1992, INT TABLES XRAY CRYS, VC

[5]

Cromer D. T., 1974, INT TABLES XRAY CRYS, V4

[6] PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE [J].

FUJITA, M ;

KWON, YJ ;

WASHIZU, S ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1151-1152

[7]

HAGRMAN D, 1997, ANGEW CHEM INT EDIT, V36, P795

[8]

HAGRMAN D, UNPUB

[9]

HAGRMAN DE, 1999, IN PRESS ANGEW CHEM

[10] Investigations of the copper bromide-2,2′-dipyridyl system:: Hydrothermal synthesis and structural characterization of molecular Cu3Br4(C10H8N2)2, one-dimensional CuBr2(C10H8N2), and two-dimensional [Cu2(OH)2(C10H8N2)2][Cu4Br6] [J].

Hammond, RP ;

Cavaluzzi, M ;

Haushalter, RC ;

Zubieta, JA .

INORGANIC CHEMISTRY, 1999, 38 (06) :1288-1292

← 1 2 →