Controllable hydrothermal synthesis of manganese dioxide nanostructures: shape evolution, growth mechanism and electrochemical properties

被引:142
作者
Duan, Xiaochuan
Yang, Jiaqin
Gao, Haiyan
Ma, Jianmin
Jiao, Lifang
Zheng, Wenjun [1 ]
机构
[1] Nankai Univ, Coll Chem, Dept Chem Mat, Key Lab Adv Energy Mat Chem MOE, Tianjin 300071, Peoples R China
来源
CRYSTENGCOMM | 2012年 / 14卷 / 12期
关键词
MNO2; NANOSTRUCTURES; OXIDE NANOPARTICLES; MAGNETIC-RESONANCE; MORPHOLOGY CONTROL; NANOWALL ARRAYS; LITHIUM; INTERCALATION; ALPHA-MNO2; NANOWIRES; STORAGE;
D O I
10.1039/c2ce06587h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, four well-defined morphologies, including nanorod, nanowire, nanoflower and nanowall, of MnO2 nanostructures with different crystal phases (alpha-, beta-, and delta-MnO2) have been synthesized employing a simple hydrothermal process. The samples are characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), energy-dispersive X-ray spectroscopy (EDS), and Brunauer-Emmett-Teller (BET) spectrometry. Our experimental results demonstrate that the concentration of KMnO4 plays a key role in forming different shapes and phases of MnO2 nanostructures. Specifically, the K+ concentration can affect the crystal phase of MnO2 seeds in the nucleation processes and the decomposition rate of MnO4- can influence the number of MnO2 nuclei at the initial nucleating stage and also can affect the subsequent crystal growth process. Moreover, the effects of reaction temperature on the morphology of the delta-MnO2 nanowall are systematically studied. The electrochemical performances of the as-prepared MnO2 as the positive material of rechargeable Li-ion batteries have also been researched. It is found that the alpha-MnO2 nanowall possesses largely enhanced electrochemical activity compared to alpha-MnO2 nanowires and beta-MnO2 nanorods. The vast difference in electrochemical activity is discussed in terms of the morphology, crystal phase and specific surface area of MnO2 nanostructures. It is highly expected that these findings are useful in understanding the formation of MnO2 nanocrystals with different morphologies, which are also applicable to other metal oxides nanocrystals.
引用
收藏
页码:4196 / 4204
页数:9
相关论文
共 54 条
[1]   Promises and problems of mesoscale materials chemistry or why meso? [J].
Antonietti, M ;
Ozin, GA .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) :28-41
[2]   Fully reversible homogeneous and heterogeneous Li storage in RuO2 with high capacity [J].
Balaya, P ;
Li, H ;
Kienle, L ;
Maier, J .
ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (08) :621-625
[3]   Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life [J].
Cao, Yuliang ;
Xiao, Lifen ;
Wang, Wei ;
Choi, Daiwon ;
Nie, Zimin ;
Yu, Jianguo ;
Saraf, Laxmikant V. ;
Yang, Zhenguo ;
Liu, Jun .
ADVANCED MATERIALS, 2011, 23 (28) :3155-+
[4]   Hydrothermal synthesis and characterization of K chi MnO2 center dot gamma H2O [J].
Chen, RJ ;
Zavalij, P ;
Whittingham, MS .
CHEMISTRY OF MATERIALS, 1996, 8 (06) :1275-1280
[5]   Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures [J].
Cölfen, H ;
Mann, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (21) :2350-2365
[6]   Hydrothermal growth of manganese dioxide into three-dimensional hierarchical nanoarchitectures [J].
Ding, YS ;
Shen, XF ;
Gomez, S ;
Luo, H ;
Aindow, M ;
Suib, SL .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (04) :549-555
[7]   Controlled preparation of MnO2 hierarchical hollow nanostructures and their application in water treatment [J].
Fei, Jinbo ;
Cui, Yue ;
Yan, Xuehai ;
Qi, Wei ;
Yang, Yang ;
Wang, Kewei ;
He, Qiang ;
Li, Junbai .
ADVANCED MATERIALS, 2008, 20 (03) :452-+
[8]   ALKALI-METAL IONS INSERTION/EXTRACTION REACTIONS WITH HOLLANDITE-TYPE MANGANESE OXIDE IN THE AQUEOUS-PHASE [J].
FENG, Q ;
KANOH, H ;
MIYAI, Y ;
OOI, K .
CHEMISTRY OF MATERIALS, 1995, 7 (01) :148-153
[9]   Structure of synthetic K-rich birnessites obtained by high-temperature decomposition of KMnO4. 2.: Phase and structural heterogeneities [J].
Gaillot, AC ;
Drits, VA ;
Plançon, A ;
Lanson, B .
CHEMISTRY OF MATERIALS, 2004, 16 (10) :1890-1905
[10]   Transition metal oxide core-shell nanowires: Generic synthesis and transport studies [J].
Han, S ;
Li, C ;
Liu, ZQ ;
Lei, B ;
Zhang, DH ;
Jin, W ;
Liu, XL ;
Tang, T ;
Zhou, CW .
NANO LETTERS, 2004, 4 (07) :1241-1246