Adsorption of equal mass fraction near an azeotropic mixture of pentafluoroethane and 1,1,1-trifluoroethane on activated carbon

被引:24
作者
Saha, Bidyut B. [1 ]
El-Sharkawy, Ibrahim I. [1 ]
Habib, Khairul [1 ]
Koyama, Shigeru [1 ]
Srinivasan, Kandadai [1 ]
机构
[1] Kyushu Univ, Interdisciplinary Grad Sch Engn Sci, Kasuga, Fukuoka 8168580, Japan
关键词
D O I
10.1021/je800204p
中图分类号
O414.1 [热力学];
学科分类号
摘要
This paper presents adsorption isotherms for R-507A, which is a near azeotropic mixture of R-125 (pentafluoroethane) and R-143a (1, 1, 1-trifluoroethane) in equal mass fractions, on a Maxsorb III specimen of activated carbon in the temperature range of about (5 to 70) degrees C and pressure up to 15 bar. The data were obtained using the desorption method to an estimated precision of 5 % and fitted to three isotherm equations, namely, Dubinin-Astakhov, Langmuir, and Toth. The adsorption parameters were determined. Some peculiarities in isosteric heating behavior were observed.
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页码:1872 / 1876
页数:5
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