Synthesis and properties of bitetraselenafulvalene

被引：17

作者：

Iyoda, M ^{[1
]}

Hara, K

Rao, CRV

Kuwatani, Y

Takimiya, K

Morikami, A

Aso, Y

Otsubo, T

机构：

[1] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan

[2] Hiroshima Univ, Fac Engn, Dept Appl Chem, Higashihiroshima 739, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 31期

关键词：

coupling reactions; electron donors; physical properties; X-ray crystal structures;

D O I：

10.1016/S0040-4039(99)01085-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper(II)- and palladium(II)-catalyzed home-coupling reactions of trimethylstannyltetraselenafulvalene proceed smoothly to produce bitetraselenafulvalene (biTSF) in good yield. The X-ray analysis of biTSF shows an interesting crystal structure. The CT-complex and radical cation salts derived from biTSF indicate fairly high electric conductivities. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：5729 / 5730

页数：2

共 11 条

[1] OLIGOMERIC TETRATHIAFULVALENES - EXTENDED DONORS FOR INCREASING THE DIMENSIONALITY OF ELECTRICAL-CONDUCTION [J].