Synthesis of stable super water- and oil-repellent polythiophene films

被引:97
作者
Nicolas, M [1 ]
Guittard, F [1 ]
Géribaldi, S [1 ]
机构
[1] Univ Nice, Lab Chim Mat Organ & Met, CMOM, EA 3155, F-06108 Nice 2, France
关键词
electrochemistry; hydrophobic effect; polymers; surface chemistry; thin films;
D O I
10.1002/anie.200503892
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) A cauliflowerlike surface (see picture, scale bar: 8 μm) and perfluorocarbon chains on the polymer backbone result in super water and oil repellency of a film of the fluorinated polythiophene shown that was electrochemically deposited on an indium tin oxide surface. The inset shows a camera image of a water droplet on the surface (contact angle > 150°). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:2251 / 2254
页数:4
相关论文
共 63 条
[1]   Substituted polythiophenes designed for optoelectronic devices and conductors [J].
Andersson, MR ;
Thomas, O ;
Mammo, W ;
Svensson, M ;
Theander, M ;
Inganäs, O .
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (09) :1933-1940
[2]  
[Anonymous], ANGEW CHEM INT ED, DOI DOI 10.1002/ANGE.200353381
[3]  
[Anonymous], ANGEW CHEM
[4]   THE ELECTRODEPOSITION OF POLYPYRROLE FILMS FROM AQUEOUS-SOLUTIONS [J].
ASAVAPIRIYANONT, S ;
CHANDLER, GK ;
GUNAWARDENA, GA ;
PLETCHER, D .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 177 (1-2) :229-244
[5]   Synthesis of azobenzene-containing polythiophenes and photoinduced anisotropy [J].
Aubertin, F ;
Zhao, Y .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (14) :3445-3455
[6]   MODIFICATION OF SURFACE-PROPERTIES OF UV-CURED FILMS IN THE PRESENCE OF LONG-CHAIN ACRYLIC-MONOMERS [J].
BONGIOVANNI, R ;
MALUCELLI, G ;
PRIOLA, A .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1995, 171 (02) :283-287
[7]   SYNTHESIS OF 3-(POLYFLUOROALKYL)THIOPHENES [J].
BUCHNER, W ;
GARREAU, R ;
RONCALI, J ;
LEMAIRE, M .
JOURNAL OF FLUORINE CHEMISTRY, 1992, 59 (03) :301-309
[8]   Ultrahydrophobic and ultralyophobic surfaces:: Some comments and examples [J].
Chen, W ;
Fadeev, AY ;
Hsieh, MC ;
Öner, D ;
Youngblood, J ;
McCarthy, TJ .
LANGMUIR, 1999, 15 (10) :3395-3399
[9]   Synthesis and characterization of three types of alkoxy-substituted hybrid PPV-PPE polymers: Potential candidates for photovoltaic applications [J].
Egbe, DAM ;
Bader, C ;
Nowotny, J ;
Klemm, E .
ORGANIC PHOTOVOLTAICS IV, 2004, 5215 :79-88
[10]  
Facchetti A, 2000, ANGEW CHEM INT EDIT, V39, P4547, DOI 10.1002/1521-3773(20001215)39:24<4547::AID-ANIE4547>3.0.CO