Platinum-catalyzed intermolecular hydroamination of unactivated olefins with carboxamides

被引：96

作者：

Wang, X ^{[1
]}

Widenhoefer, RA ^{[1
]}

机构：

[1] Duke Univ, Paul M Gross Chem Lab, Durham, NC 27708 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 08期

关键词：

D O I：

10.1021/om0498549

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of benzamide with a catalytic 1:2 mixture of [PtCl2(H2C=CH2)](2) (2.5 mol %) and PPh3 in dioxane at 120 degreesC for 24 h led to isolation of N-ethylbenzamide in 97% yield. A range of primary, acyclic aryl and alkyl carboxamides and secondary cyclic carboxamides and carbamates also underwent platinum-catalyzed addition to ethylene and propylene.

引用

页码：1649 / 1651

页数：3

共 19 条

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