Reductive elimination reaction of rhenium complexes trans-(η5-C5Me5)Re(CO)2(chloroaryl)Cl

被引：5

作者：

Aballay, Alvaro ^{[1
]}

Arancibia, Rodrigo ^{[1
]}

Buono-Core, Gonzalo E. ^{[1
]}

Cautivo, Teresa ^{[1
]}

Godoy, Fernando ^{[1
]}

Klahn, A. Hugo ^{[1
]}

Oelckers, Beatriz ^{[1
]}

机构：

[1] Pontificia Univ Catolica Valparaiso, Inst Quim, Valparaiso, Chile

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 11期

关键词：

rhenium; complexes; reductive elimination; chloroaryl-pentamethyleyclopentadiene;

D O I：

10.1016/j.jorganchem.2006.01.048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermal reaction of the chloroaryl-chloride complexes trans-(eta(5)-C5Me5)Re(CO)(2)(Ar-Cl)Cl (Ar-Cl=3-ClC6H4, 3-ClC6H3(4-Me) and 3,5-Cl2C6H3) in acetonitrile did not interconvert to the cis isomer, instead the complex ReCl(CO)(2)(NCMe)(3) and the corresponding 5-Ar-Cl-1,2,3,4,5-pentamethylcyclopentadiene were formed. Similar reductive elimination products were obtained when the starting rhenium complexes were reacted with trimethylphosphite in toluene. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：2563 / 2566

页数：4

共 15 条

[1] Selectivity in C-Cl bond activation of dichloroarenes by photogenerated Cp*Re(CO)2:: combined experimental and DFT studies [J].

Aballay, A ;

Clot, E ;

Eisenstein, O ;

Garland, MT ;

Godoy, F ;

Klahn, AH ;

Muñoz, JC ;

Oelckers, B .

NEW JOURNAL OF CHEMISTRY, 2005, 29 (01) :226-231

[2] Photochemical C-Cl bond activation of trichloroarenes by the rhenium complex (η5-C5Me5)Re(CO)3.: X-ray structure of trans-(η5-C5Me5)Re(CO)2(2-methoxy-4,5-dichlorophenyl)chloride [J].

Aballay, A ;

Godoy, F ;

Buono-Core, GE ;

Klahn, AH ;

Oelckers, B ;

Garland, MT ;

Muñoz, JC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 688 (1-2) :168-173

[3] PHOTOINDUCED INSERTION OF TUNGSTEN INTO AROMATIC AND ALIPHATIC CARBON-HYDROGEN BONDS BY BIS(ETA-CYCLOPENTADIENYL)TUNGSTEN DERIVATIVES [J].

BERRY, M ;

ELMITT, K ;

GREEN, MLH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (12) :1950-1958

[4] KINETIC GENERATION OF CIS-C5H5(CO)2REH2 FROM THE REACTION OF C5H5(CO)2RE(MU-H)PT(H)(PPH3)2 WITH DIPHENYLACETYLENE [J].

CASEY, CP ;

TANKE, RS ;

HAZIN, PN ;

KEMNITZ, CR ;

MCMAHON, RJ .

INORGANIC CHEMISTRY, 1992, 31 (26) :5474-5479

[5] Phase-dependent diagonal and lateral isomerism of the rhenium complexes (eta(5)-C(5)H(4)Me)Re(CO)(2)Br-2 [J].

Cheng, L ;

Coville, NJ .

ORGANOMETALLICS, 1996, 15 (02) :867-871

[6]

Coville NJ, 2002, EUR J INORG CHEM, P3067

[7] Perfluorobenzyl complexes of cobalt and rhodium. Unusual coupling between pentafluorophenyl and pentamethylcyclopentadienyl rings [J].

Hughes, RP ;

Lindner, DC ;

Rheingold, AL ;

Yap, GPA .

ORGANOMETALLICS, 1996, 15 (26) :5678-5686

[8]

KING RB, 1988, ORG SYNTH, V6, P39

[9]

KLAHN AH, 1993, BOL SOC CHIL QUIM, V38, P277

[10] Syntheses and reactions of the complexes (η5-C5Me5)Re(CO)2(C6Cl5-nHn)Cl (n=2,3):: Compounds derived from initial C-Cl activation [J].

Klahn, AH ;

Carreño, M ;

Godoy, F ;

Oelckers, B ;

Pizarro, A ;

Toro, A ;

Reyes, A .

JOURNAL OF COORDINATION CHEMISTRY, 2001, 54 (3-4) :379-388

← 1 2 →