Formal total synthesis of (+/-)-aflatoxin B-2 utilizing the rhodium carbenoid dipolar cycloaddition

被引:24
作者
Pirrung, MC
Lee, YR
机构
[1] Department of Chemistry, Duke University, P. M. Gross Chemical Laboratory, Durham
关键词
rhodium acetate; diazocompound; total synthesis; Baeyer-Villiger; cycloaddition;
D O I
10.1016/0040-4039(96)00412-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A formal total synthesis of (+/-)-aflatoxin B-2 has been completed using as the key step the rhodium-mediated dipolar cycloaddition of a cyclic rhodium carbenoid to dihydrofuran. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:2391 / 2394
页数:4
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