Synthesis and dye sensitized solar cell applications of Bodipy derivatives with bis-dimethylfluorenyl amine donor groups

被引:38
作者
Cakmak, Yusuf [1 ]
Kolemen, Safacan [1 ]
Buyuktemiz, Muhammed [2 ]
Dede, Yavuz [2 ]
Erten-Ela, Sule [3 ]
机构
[1] Bilkent Univ, Natl Nanotechnol Res Ctr UNAM, TR-06800 Bilkent Ankara, Turkey
[2] Gazi Univ, Dept Chem, Fac Sci, TR-06500 Ankara, Turkey
[3] Ege Univ, Inst Solar Energy, TR-35100 Izmir, Turkey
关键词
ORGANIC-DYES; EXCITED-STATES; PERFORMANCE; PHOTOVOLTAICS; ELECTRICITY; CONVERSION; CHEMISTRY; ANTENNA; DESIGN; LIGHT;
D O I
10.1039/c4nj02393e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three Bodipy dyes with strong absorptivities in the visible and near infrared regions were designed, synthesized and their potential as photosensitizers for liquid electrolyte-based dye sensitized solar cells have been evaluated. For the first time Bodipy derivatives with bis-dimethylfluorenyl amine donor groups which were known for their bulky structures as donor groups have been used together. We altered our mostly used triphenylamine group with these and investigated the dye-sensitized solar cell efficiencies of this new class of Bodipy dyes.
引用
收藏
页码:4086 / 4092
页数:7
相关论文
共 46 条
[1]   High-Performance Solution-Processed Solar Cells and Ambipolar Behavior in Organic Field-Effect Transistors with Thienyl-BODIPY Scaffoldings [J].
Bura, Thomas ;
Leclerc, Nicolas ;
Fall, Sadiara ;
Leveque, Patrick ;
Heiser, Thomas ;
Retailleau, Pascal ;
Rihn, Sandra ;
Mirloup, Antoine ;
Ziessel, Raymond .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (42) :17404-17407
[2]   Tetrastyryl-Bodipy Dyes: Convenient Synthesis and Characterization of Elusive Near IR Fluorophores [J].
Buyukcakir, Onur ;
Bozdemir, O. Altan ;
Kolemen, Safacan ;
Erbas, Sundus ;
Akkaya, Engin U. .
ORGANIC LETTERS, 2009, 11 (20) :4644-4647
[3]   Luminescence of BODIPY and Dipyrrin: An MCSCF Comparison of Excited States [J].
Buyuktemiz, Muhammed ;
Duman, Selin ;
Dede, Yavuz .
JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (07) :1665-1669
[4]   Designing Excited States: Theory-Guided Access to Efficient Photosensitizers for Photodynamic Action [J].
Cakmak, Yusuf ;
Kolemen, Safacan ;
Duman, Selin ;
Dede, Yavuz ;
Dolen, Yusuf ;
Kilic, Bilal ;
Kostereli, Ziya ;
Yildirim, Leyla Tatar ;
Dogan, A. Lale ;
Guc, Dicle ;
Akkaya, Engin U. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (50) :11937-11941
[5]   Novel organic dyes containing bis-dimethylfluorenyl amino benzo[b]thiophene for highly efficient dye-sensitized solar cell [J].
Choi, Hyunbong ;
Lee, Jae Kwan ;
Song, Kihyung ;
Kang, Sang Ook ;
Ko, Jaejung .
TETRAHEDRON, 2007, 63 (15) :3115-3121
[6]   Sensitizer molecular structure-device efficiency relationship in dye sensitized solar cells [J].
Clifford, John N. ;
Martinez-Ferrero, Eugenia ;
Viterisi, Aurelien ;
Palomares, Emilio .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (03) :1635-1646
[7]   A novel class of emitting amorphous molecular materials with bipolar character for electroluminescence [J].
Doi, H ;
Kinoshita, M ;
Okumoto, K ;
Shirota, Y .
CHEMISTRY OF MATERIALS, 2003, 15 (05) :1080-1089
[8]   Distyryl-boradiazaindacenes: facile synthesis of novel near IR emitting fluorophores [J].
Dost, Zeynep ;
Atilgan, Serdar ;
Akkaya, Engin U. .
TETRAHEDRON, 2006, 62 (36) :8484-8488
[9]   Dye Sensitized Solar Cells for Conversion of Solar Energy into Electricity [J].
Erten-Ela, S. ;
Cakir, A. Cagatay .
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2015, 37 (08) :807-816
[10]   A panchromatic boradiazaindacene (BODIPY) sensitizer for dye-sensitized solar cells [J].
Erten-Ela, Sule ;
Yilmaz, M. Deniz ;
Icli, Burcak ;
Dede, Yavuz ;
Icli, Siddik ;
Akkaya, Engin U. .
ORGANIC LETTERS, 2008, 10 (15) :3299-3302