Synthesis, photophysics and crystal structures of hexanuclear copper(I) and silver(I) acetylide complexes

被引：92

作者：

Yam, VWW

Fung, WKM

Cheung, KK

机构：

[1] Department of Chemistry, University of Hong Kong, Hong Kong, Pokfulam Road

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 10期

关键词：

BRIDGING LIGANDS; BIS(DIPHENYLPHOSPHINO)METHANE; TETRANUCLEAR; CLUSTERS;

D O I：

10.1039/a701133d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The luminescent complexes [M-3(mu-Ph2PCH2PPh2)(3)(mu(3)-eta(1)-C=CC6H4C=C-p)M-3(mu-Ph2PCH2PPh2)(3)][BF4](4) are synthesized by the reaction of [M-2(mu-Ph2PCH2PPh2)(2)(MeCN)(2)](2+) and 1,4-diethynylbenzene in the presence of (BuLi)-Li-n in thf(M = Cu 1, Ag 2); X-ray crystal structures of both are determined.

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页码：963 / 964

页数：2

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