Oxidation of primary alcohols to acyl fluorides using BrF3

被引：27

作者：

Rozen, S

BenDavid, I

机构：

[1] School of Chemistry, Raymond/Beverly Sackler Fac. of E., Tel-Aviv University

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 76卷 / 02期

基金：

以色列科学基金会;

关键词：

fluorine; bromine trifluoride; acyl fluorides; oxidation; NMR spectroscopy; IR spectroscopy;

D O I：

10.1016/0022-1139(95)03365-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aliphatic and alicyclic primary alcohols when treated with BrF3 were rapidly oxidized to the corresponding acyl fluorides. The reaction is of an ionic nature. The main by-product was found to be the symmetrical ester which originates from the reaction between the acyl fluoride and unreacted starting alcohol.

引用

页码：145 / 147

页数：3

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