Red-Green-Blue Electrogenerated Chemiluminescence Utilizing a Digital Camera as Detector

被引：104

作者：

Doeven, Egan H. ^{[1
]}

Barbante, Gregory J. ^{[1
]}

Kerr, Emily ^{[1
]}

Hogan, Conor F. ^{[2
]}

Endler, John A. ^{[3
]}

Francis, Paul S. ^{[1
]}

机构：

[1] Deakin Univ, Fac Sci Engn & Built Environm, Sch Life & Environm Sci, Ctr Chem & Biotechnol, Waurn Ponds, Vic 3216, Australia

[2] La Trobe Univ, La Trobe Inst Mol Sci, Dept Chem, Bundoora, Vic 3086, Australia

[3] Deakin Univ, Fac Sci Engn & Built Environm, Ctr Integrat Ecol, Waurn Ponds, Vic 3216, Australia

来源：

ANALYTICAL CHEMISTRY | 2014年 / 86卷 / 05期

基金：

澳大利亚研究理事会;

关键词：

SELECTIVE EXCITATION; ELECTROCHEMILUMINESCENCE; TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II);

D O I：

10.1021/ac404135f

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Exploiting the distinct excitation and emission properties of concomitant electrochemiluminophores in conjunction with the inherent color selectivity of a conventional digital camera, we create a new strategy for multiplexed electrogenerated chemiluminescence detection, suitable for the development of low-cost, portable clinical diagnostic devices. Red, green and blue emitters can be efficiently resolved over the three-dimensional space of ECL intensity versus applied potential and emission wavelength. As the relative contribution ratio of each emitter to the photographic RGB channels is constant, the RGB ECL intensity versus applied-potential curves could be effectively isolated to a single emitter at each potential.

引用

页码：2727 / 2732

页数：6

共 39 条

[1] Understanding Electrogenerated Chemiluminescence Efficiency in Blue-Shifted Iridium(III)-Complexes: An Experimental and Theoretical Study [J].