Complexes of tris(pentafluorophenyl)boron with nitrogen-containing compounds: Synthesis, reactivity and metallocene activation

被引：175

作者：

Focante, F

Mercandelli, P

Sironi, A

Resconi, L

机构：

[1] Basell Polyolefins, Ctr Ric G Natta, I-44100 Ferrara, Italy

[2] Univ Bologna, Dipartimento Chim Organ A Mangini, I-40136 Bologna, Italy

[3] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

来源：

COORDINATION CHEMISTRY REVIEWS | 2006年 / 250卷 / 1-2期

关键词：

perfluoroarylboranes; boron-nitrogen complexes; Lewis acid-Lewis base adducts; metallocenes; ion pairs;

D O I：

10.1016/j.ccr.2005.05.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The strong Lewis acid tris(pentafluorophenyl)boron, B(C6F5)(3), reacts with several nitrogen-containing Lewis bases (nitriles, amines, imines, pyridines, etc.) and also with non-basic substrates (such as pyrroles and indoles) producing in both cases the B-N coordination adduct. With particular substrates (some tertiary amines, the imine 'Bu(Me)C=NBn, N-methyl-pyrrole and -indole,) the 1:1 borane/N-compound reaction produces zwitterions where a new B-C bond is generated. Some of the borane-N-compound adducts present Bronsted acidity and can be reacted with di-methyl group 4 complexes with generation of weakly associated ion pairs, which are active catalysts for the polymerization of olefins. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：170 / 188

页数：19

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