Oxidative coupling of platinum arylamides:: temperature dependent C-H or C-F cleavage

被引：5

作者：

Albéniz, AC ^{[1
]}

Calle, V ^{[1
]}

Espinet, P ^{[1
]}

Gómez, S ^{[1
]}

机构：

[1] Univ Valladolid, Fac Ciencias, Dept Quim Inorgan, E-47005 Valladolid, Spain

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b110909j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of an arylamido platinum complex leads to CC coupling with selective C-H versus C-F bond cleavage depending on the reaction temperature.

引用

页码：610 / 611

页数：2

共 18 条

[1] The origin of hindered rotation around the Pt-N bond in platinum amides [J].

Albéniz, AC ;

Calle, V ;

Espinet, P ;

Gómez, S .

INORGANIC CHEMISTRY, 2001, 40 (17) :4211-4216

[2] Dynamics of bond breaking in ion radicals. Mechanisms and reactivity in the reductive cleavage of carbon-fluorine bonds of fluoromethylarenes [J].

Andrieux, CP ;

Combellas, C ;

Kanoufi, F ;

Saveant, JM ;

Thiebault, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (40) :9527-9540

[3] ANODIC OXIDATIONS OF AROMATIC AMINES .3. SUBSTITUTED ANILINES IN AQUEOUS MEDIA [J].

BACON, J ;

ADAMS, RN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (24) :6596-&

[4] Recent advances in C-F bond activation [J].

Burdeniuc, J ;

Jedlicka, B ;

Crabtree, RH .

CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (02) :145-154

[5] Catalytic photodefluorination of perfluoroalkanes to perfluoroalkenes with a ferrocene photosensitizer [J].

Burdeniuc, J ;

Crabtree, RH .

ORGANOMETALLICS, 1998, 17 (08) :1582-1586

[6] NEW REACTION OF SATURATED FLUOROCARBONS - PARTIAL REDUCTION BY NH3 WITH HG PHOTOSENSITIZATION [J].

BURDENIUC, J ;

CHUPKA, W ;

CRABTREE, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (40) :10119-10120

[7] THE OXIDATIVE DIMERIZATION OF ARYLAMIDO COMPLEXES OF PLATINUM REVISITED - PROTONATION DEPROTONATION OR OXIDATION REDUCTION [J].

ESPINET, P ;

GARCIAHERBOSA, G ;

RAMOS, JM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (09) :2931-2933

[8] DOUBLE OXIDATIVE CARBON CARBON COUPLING OF A DIMERIC ORTHOPALLADATED AMIDO COMPLEX LEADING TO REDOX-ACTIVE TETRAPALLADIA UNITS [PD4](N+) (N = 0-4) [J].

ESPINET, P ;

ALONSO, MY ;

GARCIAHERBOSA, G ;

RAMOS, JM ;

JEANNIN, Y ;

PHILOCHELEVISALLES, M .

INORGANIC CHEMISTRY, 1992, 31 (12) :2501-2507

[9] LATE TRANSITION-METAL MU-OXO AND MU-IMIDO COMPLEXES .14. OXIDATIVE COUPLING OF RHODIUM PHENYL IMIDO/AMIDO COMPLEXES [J].

GE, YW ;

YE, Y ;

SHARP, PR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) :8384-8385

[10] ELECTROCHEMICAL OXIDATION OF POLYFLUOROAROMATIC AMINES .1. SYNTHESIS OF FLUOROPHENAZINES [J].

HUDSON, AG ;

PEDLER, AE ;

TATLOW, JC .

TETRAHEDRON, 1970, 26 (15) :3791-&

← 1 2 →