Preparation and characterisation of a highly active bimetallic (Pd-Ru) nanoparticle heterogeneous catalyst

被引：132

作者：

Raja, R

Sankar, G

Hermans, S

Shephard, DS

Bromley, S

Thomas, JM

Johnson, BFG

机构：

[1] UCL Royal Inst Great Britain, Davy Faraday Res Lab, London W1X 4BS, England

[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 16期

关键词：

D O I：

10.1039/a901263j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mixed-metal carbonylate cluster [Pd6Ru6(CO)(24)](2-) was used as a single-source precursor in the synthesis of a highly active hydrogenation catalyst (stoichiometry PdRu) which has been characterised by electron microscopy and X-ray absorption spectroscopy: PdRu readily hydrogenates alkenes and naphthalene (the latter predominantly to cis-decalin) under mild conditions.

引用

页码：1571 / 1572

页数：2

共 19 条

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