Sonochemical synthesis of tungsten sulfide nanorods

被引：51

作者：

Nikitenko, SI

Koltypin, Y

Mastai, Y

Koltypin, M

Gedanken, A ^{[1
]}

机构：

[1] Bar Ilan Univ, Dept Chem, Ramat Gan, Israel

[2] RAS, Inst Phys Chem, Moscow 117901, Russia

[3] Max Planck Inst Colloids & Interfaces, Golm, Germany

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2002年 / 12卷 / 05期

关键词：

D O I：

10.1039/b110867k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Amorphous WS2 has been prepared by ultrasound irradiation of W(CO)(6) solution in diphenylmethane (DPhM) in the presence of a slight excess of sulfur at 90 degreesC under argon. Heating the amorphous powder at 800 degreesC under argon yields WS2 nanorods and their packings. The average size of WS2 nanorods was found to be 3-10 nm and 1-5 mum in thickness and length, respectively. The prepared WS2 has been characterized by elemental analysis, X-ray powder diffraction measurements, FTIR spectroscopy, differential scanning calorimetry, thermogravimetric analysis, transmission electron microscopy, scanning electron microscopy, atomic force microscopy and energy dispersive X-ray analysis.

引用

收藏

页码：1450 / 1452

页数：3

相关论文

共 25 条

[1] Preparation of MoS2 and WS2 catalysts by in situ decomposition of ammonium thiosalts [J].

Alonso, G ;

Del Valle, M ;

Cruz, J ;

Licea-Claverie, A ;

Petranovskii, V ;

Fuentes, S .

CATALYSIS LETTERS, 1998, 52 (1-2) :55-61

[2] Preparation of WS2 catalysts by in situ decomposition of tetraalkylammonium thiotungstates [J].

Alonso, G ;

Petranovskii, V ;

Del Valle, M ;

Cruz-Reyes, J ;

Licea-Claverie, A ;

Fuentes, S .

APPLIED CATALYSIS A-GENERAL, 2000, 197 (01) :87-97

[3]

Bailar J.C., 1973, COMPREHENSIVE INORGA

[4] Optical and electrical properties of semiconducting WS2 thin films:: From macroscopic to local probe measurements [J].

Ballif, C ;

Regula, M ;

Lévy, F .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1999, 57 (02) :189-207

[5] WS2 thin films by metal organic chemical vapor deposition [J].

Chung, JW ;

Dai, ZR ;

Ohuchi, FS .

JOURNAL OF CRYSTAL GROWTH, 1998, 186 (1-2) :137-150

[6] Sonochemical preparation of supported hydrodesulfurization catalysts [J].

Dhas, NA ;

Ekhtiarzadeh, A ;

Suslick, KS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (34) :8310-8316

[7] PREPARATION OF TEXTURED AND PHOTOACTIVE 2H-WS2 THIN-FILMS BY SULFURIZATION OF WO3 [J].

ENNAOUI, A ;

FIECHTER, S ;

ELLMER, K ;

SCHEER, R ;

DIESNER, K .

THIN SOLID FILMS, 1995, 261 (1-2) :124-131

[8] New reactor for production of tungsten disulfide hollow onion-like (inorganic fullerene-like) nanoparticles [J].

Feldman, Y ;

Zak, A ;

Popovitz-Biro, R ;

Tenne, R .

SOLID STATE SCIENCES, 2000, 2 (06) :663-672

[9] Bulk synthesis of inorganic fullerene-like MS(2) (M=Mo, W) from the respective trioxides and the reaction mechanism [J].

Feldman, Y ;

Frey, GL ;

Homyonfer, M ;

Lyakhovitskaya, V ;

Margulis, L ;

Cohen, H ;

Hodes, G ;

Hutchison, JL ;

Tenne, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (23) :5362-5367

[10] Nanostructured molybdenum carbide: Sonochemical synthesis and catalytic properties [J].

Hyeon, TH ;

Fang, MM ;

Suslick, KS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (23) :5492-5493