Use of 9-anthrylcarbinol derivatives as chiral auxiliaries .2. Asymmetric 1,3-dipolar cycloaddition

被引：15

作者：

Carriere, A

Virgili, A

Figueredo, M

机构：

[1] Dept. de Química Organica, Univ. Autònoma de Barcelona, 08193 Bellaterra, Barcelona

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 10期

关键词：

D O I：

10.1016/0957-4166(96)00364-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1,3-dipolar cycloaddition of acrylates derived from 9-anthrylcarbinol to a cyclic nitrone is studied. The composition of the reaction product depends on the steric hindrance of the substituent. A complete study of the diastereoisomers was performed by NMR and we were thus able to determine the absolute configuration of the major adducts. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：2793 / 2796

页数：4

共 10 条

[1]

ALI SA, 1988, TETRAHEDRON, V44, P5911

[2] Use of 9-anthrylcarbinol derivatives as chiral auxiliaries in asymmetric Diels-Alder reaction [J].