Synthesis and Electrochemical Reaction with Lithium of Mesoporous Iron Oxalate Nanoribbons

被引：97

作者：

Jose Aragon, Maria ^{[1
]}

Leon, Bernardo ^{[1
]}

Perez Vicente, Carlos ^{[1
]}

Tirado, Jose L. ^{[1
]}

机构：

[1] Univ Cordoba, Lab Quim Inorgan, E-14071 Cordoba, Spain

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 22期

关键词：

D O I：

10.1021/ic8008927

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Mesoporous FeC2O4 was prepared by dehydration of bulk monoclinic- and micellar orthorhombic FeC2O4 center dot 2H(2)O precursors at 200 degrees C. The micellar material shows nanoribbon shaped particles, which are preserved after dehydration. These solids are used as high-capacity lithium storage materials with improved rate performance. The mesoporous nanoribbons exhibit higher capacities close to 700 mA h/g after 50 cycles at 2C (C = 1 Li h(-1) mol(-1)) rate between 0 and 2 V.

引用

页码：10366 / 10371

页数：6

共 22 条

[1]

Changes in oxidation state and magnetic order of iron atoms during the electrochemical reaction of lithium with NiFe2O4 [J].

Alcántara, R ;

Jaraba, M ;

Lavela, P ;

Tirado, JL ;

Jumas, JC ;

Olivier-Fourcade, J .

ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (01) :16-21

[2]

NiCo2O4 spinel:: First report on a transition metal oxide for the negative electrode of sodium-ion batteries [J].

Alcántara, R ;

Jaraba, M ;

Lavela, P ;

Tirado, JL .

CHEMISTRY OF MATERIALS, 2002, 14 (07) :2847-+

[3]

Submicronic particles of manganese carbonate prepared in reverse micelles:: A new electrode material for lithium-ion batteries [J].

Aragon, M. J. ;

Perez-Vicente, C. ;

Tirado, J. L. .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (07) :1744-1748

[4]

RESONANT-GAMMA-RAY ABSORPTION IN IRON OXALATE [J].

ARAMU, F ;

MAXIA, V ;

MUNTONI, C .

LETTERE AL NUOVO CIMENTO, 1975, 12 (07) :225-227

[5]

Lithium-ion intercalation into TiO2-B nanowires [J].

Armstrong, AR ;

Armstrong, G ;

Canales, J ;

García, R ;

Bruce, PG .

ADVANCED MATERIALS, 2005, 17 (07) :862-+

[6]

Structure and electrochemistry of copper fluoride nanocomposites utilizing mixed conducting matrices [J].

Badway, F. ;

Mansour, A. N. ;

Pereira, N. ;

Al-Sharab, J. F. ;

Cosandey, F. ;

Plitz, I. ;

Amatucci, G. G. .

CHEMISTRY OF MATERIALS, 2007, 19 (17) :4129-4141

[7]

57Fe Mossbauer Spectroscopy and electron Microscopy study of metal extraction from CuFe2O4 electrodes in lithium cells [J].

Bomio, Mauricio ;

Lavela, Pedro ;

Tirado, Jose Luis .

CHEMPHYSCHEM, 2007, 8 (13) :1999-2007

[8]

SURFACE ADSORPTION OF 57CO-57FE ON IRON(2) + COBALT)2) OXALATES [J].

BRADY, PR ;

DUNCAN, JF .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (FEB) :653-&

[9]

THERMAL DECOMPOSITION OF FERROUS OXALATE DIHYDRATE [J].

BROWN, RA ;

BEVAN, SC .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1966, 28 (02) :387-&

[10]

High-performance lithium battery anodes using silicon nanowires [J].

Chan, Candace K. ;

Peng, Hailin ;

Liu, Gao ;

McIlwrath, Kevin ;

Zhang, Xiao Feng ;

Huggins, Robert A. ;

Cui, Yi .

NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35

← 1 2 3 →