Four-electron reduction of dioxygen catalyzed by a decavanadium complex

被引：8

作者：

Dewi, EL ^{[1
]}

Oyaizu, K ^{[1
]}

Tsuchida, E ^{[1
]}

机构：

[1] Waseda Univ, Dept Polymer Chem, Adv Res Inst Sci & Engn, Tokyo 1698555, Japan

来源：

INORGANICA CHIMICA ACTA | 2003年 / 342卷

关键词：

electrochemistry; four-electron reduction; dioxygen; decavanadium;

D O I：

10.1016/S0020-1693(02)01158-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electroreduction of O-2 in acidic aqueous solutions at an electrode modified with a decavanadium cluster [(V=O)(10)(mu(2)-O)(9)(mu(3)-O)(3)(C5H7O2)(6)] (1) revealed that it produces H2O with four electrons per O-2 molecule near 0.5 V versus SCE. The usefulness of the complex as a reduction catalyst of O-2 with a high selectivity was demonstrated. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：316 / 318

页数：3

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