Palladium-catalyzed acetoxylation of cyclic allyl phosphonates in the presence of isopentyl nitrite and using molecular oxygen as final oxidant

被引：11

作者：

Attolini, M ^{[1
]}

Peiffer, G ^{[1
]}

Maffei, M ^{[1
]}

机构：

[1] Fac St Jerome, Lab Organo Phosphores, CNRS, ESA 6009, F-13397 Marseille 20, France

来源：

TETRAHEDRON | 2000年 / 56卷 / 17期

关键词：

palladium-catalyzed acetoxylation; cyclic dialkyl allyl phosphonates; isopentyl nitrite; 3-acetoxy-1-alkenyl phosphonates;

D O I：

10.1016/S0040-4020(00)00172-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium-catalyzed acetoxylation of cyclic dialkyl allyl phosphonates is effected using palladium chloride as catalyst, in the presence of isopentyl nitrite in acetic acid under an oxygen atmosphere. The proposed mechanism for the reaction involves a palladium nitro-nitroso redox couple. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：2693 / 2697

页数：5

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