Axially chiral NHC-Pd(II) complexes in the oxidative kinetic resolution of secondary alcohols using molecular oxygen as a terminal oxidant

被引：96

作者：

Chen, Tao

Jiang, Jia-Jun

Xu, Qin

Shi, Min

机构：

[1] E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 05期

关键词：

D O I：

10.1021/ol063061w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Axially chiral N-heterocyclic carbene (NHC) Pd(II) complexes were prepared from optically active 1,1'-binaphthalenyl-2,2'-diamine (BINAM) and H-8-BINAM and applied in the oxidative kinetic resolution of secondary alcohols using molecular oxygen as a terminal oxidant. The corresponding sec-alcohols can be obtained in good yields with moderate to good enantioselectivities.

引用

页码：865 / 868

页数：4

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