Catalytic chain transfer in free-radical polymerizations

被引：332

作者：

Gridnev, AA

Ittel, SD

机构：

[1] DuPont Performance Coatings, Philadelphia, PA 19146 USA

[2] Dupont Co Inc, Cent Res & Dev, Expt Stn, Wilmington, DE 19880 USA

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 12期

关键词：

D O I：

10.1021/cr9901236

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic chain transfer (CCT) in free-radical polymerization was discussed. CCT allows the synthesis of the large variety of structured polymers. Results showed that CCT controls molecular weight in free-radical polymerization without the use of stoichiometric chain terminations.

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页码：3611 / 3659

页数：49

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