On the Use of Porous and Nonporous Fillers in the Fabrication of Silicon Carbide Membranes

被引:23
作者
Elyassi, Bahman [1 ,2 ]
Deng, Wangxue [1 ]
Sahimi, Muhammad [1 ]
Tsotsis, Theodore T. [1 ]
机构
[1] Univ So Calif, Mork Family Dept Chem Engn & Mat Sci, Los Angeles, CA 90089 USA
[2] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA
基金
美国国家科学基金会;
关键词
GAS PERMEATION PROPERTIES; WALLED CARBON NANOTUBES; SIC-BASED MEMBRANE; MICROPOROUS MEMBRANES; HYDROGEN SEPARATION; POLYCARBOSILANE; POLYDIMETHYLSILANE; PURIFICATION; TEMPERATURE; PRECURSOR;
D O I
10.1021/ie401116b
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Hydrogen-permselective asymmetric silicon carbide (SiC) membranes were prepared in this study by incorporating highly porous SiC nanofibers into the membrane structure using a sacrificial interlayer-based technique. The resulting membranes were characterized with permeation studies, nitrogen adsorption experiments, and electron microscopy analysis. Their characteristics were compared with those of SiC membranes prepared with the same approach but making use, instead, of fine, nonporous SiC powders as fillers.
引用
收藏
页码:10269 / 10275
页数:7
相关论文
共 35 条
[1]   Permeation properties of microporous membranes prepared via coating of evaporated polydimethylsilane [J].
Chen, CL ;
Tsai, DS .
JOURNAL OF MEMBRANE SCIENCE, 2004, 237 (1-2) :163-165
[2]   Preparation and reactive applications of nanoporous silicon carbide membranes [J].
Ciora, RJ ;
Fayyaz, B ;
Liu, PKT ;
Suwanmethanond, V ;
Mallada, R ;
Sahimi, M ;
Tsotsis, TT .
CHEMICAL ENGINEERING SCIENCE, 2004, 59 (22-23) :4957-4965
[3]   A novel sacrificial interlayer-based method for the preparation of silicon carbide membranes [J].
Elyassi, Bahman ;
Sahimi, Muhammad ;
Tsotsis, Theodore T. .
JOURNAL OF MEMBRANE SCIENCE, 2008, 316 (1-2) :73-79
[4]   Silicon carbide membranes for gas separation applications [J].
Elyassi, Bahman ;
Sahimi, Muhammad ;
Tsotsis, Theodore T. .
JOURNAL OF MEMBRANE SCIENCE, 2007, 288 (1-2) :290-297
[5]   Effect of polystyrene on the morphology and physical properties of silicon carbide nanofibers [J].
Elyassi, Bahman ;
Kim, Tae Wook ;
Sahimi, Muhammad ;
Tsotsis, Theodore T. .
MATERIALS CHEMISTRY AND PHYSICS, 2009, 118 (01) :259-263
[6]   Recent advances on membranes and membrane reactors for hydrogen production [J].
Gallucci, Fausto ;
Fernandez, Ekain ;
Corengia, Pablo ;
Annaland, Martin van Sint .
CHEMICAL ENGINEERING SCIENCE, 2013, 92 :40-66
[7]  
Interrante L.V., 1994, MRS Proceedings, P139, DOI DOI 10.1557/PROC-365-139
[8]  
INTERRANTE LV, 1994, MATER RES SOC SYMP P, V346, P593
[9]   Investigation of the properties of SiC membrane on alumina by using polycarbosilane [J].
Kita, K. ;
Kondo, N. ;
Izutsu, Y. ;
Kita, H. .
MATERIALS LETTERS, 2012, 75 :134-136
[10]  
Lee LL, 1999, J AM CERAM SOC, V82, P2796