Performance analysis of cobalt-based cathode materials for solid oxide fuel cell

被引：40

作者：

Kim, Jung Hyun ^{[1
]}

Baek, Seung-Wook ^{[1
]}

Lee, Changbo ^{[1
]}

Park, Kwanglin ^{[1
]}

Bae, Joongmyeon ^{[1
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Mech Engn, Taejon 305701, South Korea

来源：

SOLID STATE IONICS | 2008年 / 179卷 / 27-32期

关键词：

solid oxide fuel cell (SOFC); perovskite; spinel; X-ray photoelectron spectroscopy (XPS); area specific resistance (ASR);

D O I：

10.1016/j.ssi.2008.01.086

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The area specific resistance (ASR) characteristics of Ln(1-x)Sr(x)M ' M1-y"O-y(3-delta) (Ln=Lanthanides, M' and M": transition metal such as Co and Fe), Sm0.5Sr1.5Co1-yNiyO4-delta and Sm0.5Sr1.5Co1-yFeyO4-delta oxides were investigated as cathode materials for intermediate temperature operating solid oxide fuel cell (IT-SOFC) application. As an effect of Sr substitution in A-site of perovskite, ASR of Nd0.5Sr0.5CoO3 (NSC55) was 0.14 Omega cm(2) at 700 degrees C. Sm0.5Sr0.5CoO3-delta (SSC55) on Ce0.9Gd0.1O2-delta (CGO91) and Ce0.8Sm0.2O2-delta (CSO82) showed the lowest ASR as 0.10 Omega cm(2) and 0.085 Omega cm(2) at 700 degrees C among various perovskite compositions in this study. ASR of B-site substituted Pr0.3Sr0.7Co0.3Fe0.7O3-delta (PSCF3737) in the Pr0.3Sr0.7Co1-yFeyO3-delta Was about 0. 13 Omega cm(2) at 700 degrees C. Comparing ASR of SSC55 as a perovskite structure with the value Of Sm0.5Sr1.5Co1-yFeyO4-delta (y=0, 0.3, 0.5 and 0.7) as a spinel structure, the ASR of SSC55 was 0.085 Omega cm(2). However, the value of Sm0.5Sr1.5Co1-yFeyO4-delta (y=0, 0.3, 0.5 and 0.7) was much higher than SSC55 at 700 degrees C. In XPS analyses, the atomic percentage values of PSC55 and PSC37 were 83.5, and 83.1%. However, the value of SrCoO3-delta was 50.2%. The results claim that more oxygen sites including oxygen vacancies on the surface of PSC55 and PSC37 exist than that of SrCoO3-delta (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1490 / 1496

页数：7

共 19 条

[1] Oxides of the AMO3 and A2MO4-type:: structural stability, electrical conductivity and thermal expansion [J].

Al Daroukh, M ;

Vashook, VV ;

Ullmann, H ;

Tietz, F ;

Raj, IA .

SOLID STATE IONICS, 2003, 158 (1-2) :141-150

[2] Properties of La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) double layer cathodes on gadolinium-doped cerium oxide (CGO) electrolytes -: I.: Role of SiO2 [J].

Bae, JM ;

Steele, BCH .

SOLID STATE IONICS, 1998, 106 (3-4) :247-253

[3] GLYCINE NITRATE COMBUSTION SYNTHESIS OF OXIDE CERAMIC POWDERS [J].

CHICK, LA ;

PEDERSON, LR ;

MAUPIN, GD ;

BATES, JL ;

THOMAS, LE ;

EXARHOS, GJ .

MATERIALS LETTERS, 1990, 10 (1-2) :6-12

[4] Electrochemical behavior of Ln0.6Sr0.4Co0.2Fe0.8O3-δ (Ln = Ce, Gd, Sm, Dy) materials used as cathode of IT-SOFC [J].

Gao, JF ;

Liu, XQ ;

Peng, DK ;

Meng, GY .

CATALYSIS TODAY, 2003, 82 (1-4) :207-211

[5] CHARACTERIZATION OF NICO2O4 ELECTRODES FOR O-2 EVOLUTION .2. NONELECTROCHEMICAL CHARACTERIZATION OF NICO2O4 ELECTRODES [J].

HAENEN, J ;

VISSCHER, W ;

BARENDRECHT, E .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 208 (02) :297-321

[6] COMPARISON OF MATERIALS AS OXYGEN CATALYTIC ELECTRODES ON ZIRCONIA ELECTROLYTE [J].

ISAACS, HS ;

OLMER, LJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1982, 129 (02) :436-443

[7] ELECTRODE-REACTIONS AT SOLID OXIDE ELECTROLYTES [J].

ISAACS, HS ;

OLMER, LJ ;

SCHOULER, EJL ;

YANG, CY .

SOLID STATE IONICS, 1981, 3-4 (AUG) :503-507

[8] Performance/structure correlation for composite SOFC cathodes [J].

Juhl, M ;

Primdahl, S ;

Manon, C ;

Mogensen, M .

JOURNAL OF POWER SOURCES, 1996, 61 (1-2) :173-181

[9] Characterization of Nd0.6Sr0.4Co1-yFeyO3-δ (0 ≤ y ≤ 0.5) cathode materials for inten-nediate temperature solid oxide fuel cells [J].

Lee, KT ;

Manthiram, A .

SOLID STATE IONICS, 2005, 176 (17-18) :1521-1527

[10]

Murray EP, 2001, SOLID STATE IONICS, V143, P265, DOI 10.1016/S0167-2738(01)00871-2

← 1 2 →