Magnesium/methanol: Sn effective reducing agent for peroxides

被引：33

作者：

Dai, P ^{[1
]}

Dussault, PH ^{[1
]}

Trullinger, TK ^{[1
]}

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 08期

关键词：

D O I：

10.1021/jo035191d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Magnesium in methanol is an effective reagent for the chemoselective reduction of peroxides, including ozonides. Mg/MeOH is significantly more reactive than Me2S or PPh3 and somewhat more reactive than Zn/HOAc.

引用

页码：2851 / 2852

页数：2

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