Determining the charge distribution in BEDT-TTF salts

被引：316

作者：

Guionneau, P

Kepert, CJ

Bravic, G

Chasseau, D

Truter, MR

Kurmoo, M

Day, P

机构：

[1] ROYAL INST GREAT BRITAIN, LONDON W1X 4BS, ENGLAND

[2] UNIV OXFORD, INORGAN CHEM LAB, OXFORD OX1 3QR, ENGLAND

[3] UCL, CHRISTOPHER INGOLD LABS, LONDON W1CH 0AS, ENGLAND

来源：

SYNTHETIC METALS | 1997年 / 86卷 / 1-3期

关键词：

organic conductors; crystal structures;

D O I：

10.1016/S0379-6779(97)80983-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The intramolecular bond lengths of the donor BEDT-TTF (bis(ethylenedithio)tetrathiafulvalene, also ET) are sensitive to the charge carried by the molecule. By considering a large number of ET salts, we have developed a method for determining experimentally the charges of the ET molecules. The standard deviation in charge is only 0.1 for high quality structures.

引用

页码：1973 / 1974

页数：2

共 18 条

[1] STRUCTURE OF DI[3,4,3',4'-BIS(ETHYLENEDITHIO)-2,2',5,5'-TETRATHIAFULVALENIUM] DI-MU-IODO-BIS[DIIODOCADMATE(II)], (BEDT-TTF)2[CD2I6]
BU, XH
SU, ZW
COPPENS, P
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 279 - 282
[2] STRUCTURE AND PROPERTIES OF TRIS[BIS(ETHYLENEDITHIO)TETRATHIAFULVALENIUM]TETRACHLOROCOPPER(II) HYDRATE, (BEDT-TTF)3CUCL4.H2O - 1ST EVIDENCE FOR COEXISTENCE OF LOCALIZED AND CONDUCTION ELECTRONS IN A METALLIC CHARGE-TRANSFER SALT
DAY, P
KURMOO, M
MALLAH, T
MARSDEN, IR
FRIEND, RH
PRATT, FL
HAYES, W
CHASSEAU, D
GAULTIER, J
BRAVIC, G
DUCASSE, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10722 - 10729
[3] STRUCTURES AT 293-K AND 100-K OF BETA-TETRAKIS[BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE] TETRACYANONICKELATE(II) - BETA-[BEDT-TTF]4[NI(CN)4]
FETTOUHI, M
OUAHAB, L
GRANDJEAN, D
TOUPET, L
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1993, 49 : 685 - 691
[4] BOND LENGTHS AND CHARGE-TRANSFER IN TETRACYANOQUINODIMETHANE SALTS
FLANDROIS, S
CHASSEAU, D
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (SEP15): : 2744 - 2750
[5] STRUCTURE OF DI[3,4-3',4'-BIS(ETHYLENEDITHIO)-2,2',5,5'-TETRATHIAFULVALENIUM] TETRAIODOGALLATE(III), (BEDT-TTF)2GAI4
GEISER, U
WANG, HH
SCHLUETER, JA
HALLENBECK, SL
ALLEN, TJ
CHEN, MY
KAO, HCI
CARLSON, KD
GERDOM, LE
WILLIAMS, JM
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 : 1544 - 1547
[6] CRYSTAL-STRUCTURE OF THE SPIN-PEIERLS COMPOUND ALPHA'-(BEDT-TTF)(2)AG(CN)(2) AT HIGH-PRESSURE AND LOW-TEMPERATURE
GUIONNEAU, P
GAULTIER, J
RAHAL, M
BRAVIC, G
MELLADO, JM
CHASSEAU, D
DUCASSE, L
KURMOO, M
DAY, P
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (10) : 1639 - 1645
[7] GUIONNEAU P, 1996, THESIS U BORDEAUX 1
[8] GUIONNEAU P, 1996, IN PRESS J PHYS FRAN
[9] HEBRARD S, IN PRESS ACTA CRYST
[10] KEPERT CJ, 1996, THESIS U LONDON UK

← 1 2 →