Chemical Management for Colorful, Efficient, and Stable Inorganic-Organic Hybrid Nanostructured Solar Cells

被引:4170
作者
Noh, Jun Hong [1 ]
Im, Sang Hyuk [2 ]
Heo, Jin Hyuck [1 ]
Mandal, Tarak N. [1 ]
Seok, Sang Il [1 ,3 ]
机构
[1] Korea Res Inst Chem Technol, Div Adv Mat, Taejon 305600, South Korea
[2] Kyung Hee Univ, Dept Chem Engn, Coll Engn, Youngin Si 446701, Gyeonggi Do, South Korea
[3] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440746, South Korea
基金
新加坡国家研究基金会;
关键词
Inorganic-organic hybrid; nanostructured; colorful; efficient and stable solar cells; CRYSTALS;
D O I
10.1021/nl400349b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chemically tuned inorganic-organic hybrid materials, based on CH3NH3(=MA)Pb(I1-xBrx)(3) perovskites, have been studied using UV-vis absorption and X-ray diffraction patterns and applied to nanostructured solar cells. The band gap engineering brought about by the chemical management of MAPb(I1-xBrx)(3) perovskites can be controllably tuned to cover almost the entire visible spectrum, enabling the realization of colorful solar cells. We demonstrate highly efficient solar cells exhibiting 12.3% in a power conversion efficiency of under standard AM 1.5, for the most efficient device, as a result of tunable composition for the light harvester in conjunction with a mesoporous TiO2 film and a hole conducting polymer. We believe that the works highlighted in this paper represent one step toward the realization of low-cost, high-efficiency, and long-term stability with colorful solar cells.
引用
收藏
页码:1764 / 1769
页数:6
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