Anionic ring-opening polymerization (ROP) of a phosphorus-bridged [1]ferrocenophane initiated by living polystyrene and polyisoprene: Synthesis of novel organic-poly(ferrocenylphosphine) block copolymers

被引：11

作者：

Cao, L ^{[1
]}

Winnik, MA ^{[1
]}

Manners, I ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS | 1998年 / 8卷 / 04期

基金：

加拿大自然科学与工程研究理事会;

关键词：

anionic polymerization; block copolymer; ring-opening polymerization; poly(ferrocene); nanostructures;

D O I：

10.1023/A:1021484010088

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The novel block copolymers, polystyrene-b-poly(ferrocenylphosphine) and polyisoprene-b-poly(ferrocenylphosphine), were synthesized by anionic polymerization, utilizing the living organic anions to initiate the ring-opening polymerization of a phosphorus-bridged [1]ferrocenophane. The resulting block copolymers possess narrow polydispersities and have potentially coordinating phosphorus sites in the polymer backbone. These materials are of interest as precursors to metallized self-assembled nanoscale architectures.

引用

页码：215 / 224

页数：10

共 14 条

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