Surface vibrational spectroscopy of sulfuric acid-water mixtures at the liquid-vapor interface

被引：103

作者：

Raduge, C ^{[1
]}

Pflumio, V ^{[1
]}

Shen, YR ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,DIV MAT SCI,DEPT PHYS,BERKELEY,CA 94720

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 274卷 / 1-3期

关键词：

D O I：

10.1016/S0009-2614(97)00631-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared-visible sum-frequency generation has been used to obtain vibrational spectra of sulfuric acid-water mixtures at the liquid-vapor interface in the OH stretch region. The spectral peaks gradually disappear with increase of sulfuric acid concentration. the dangling OH mode first, followed by the bonded OM modes. Thp results can be understood if the Liquid surfaces are assumed to possess a more or less ordered hydrogen-bonding network, (C) 1997 Published by Elsevier Science B.V.

引用

页码：140 / 144

页数：5

共 27 条

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