Borrowing hydrogen: iridium-catalysed reactions for the formation of C-C bonds from alcohols

被引：92

作者：

Black, PJ ^{[1
]}

Cami-Kobeci, G ^{[1
]}

Edwards, MG ^{[1
]}

Slatford, PA ^{[1
]}

Whittlesey, MK ^{[1
]}

Williams, JMJ ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2006年 / 4卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b511053j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alcohols have been employed as substrates for C - C bond- forming reactions which involve initial activation by the temporary removal of hydrogen to form an aldehyde. The intermediate aldehyde is converted into an alkene via a Horner - Wadsworth - Emmons reaction, nitroaldol and aldol reactions. The 'borrowed hydrogen' is then returned to the alkene to form a C - C bond.

引用

页码：116 / 125

页数：10

共 41 条

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