Intermolecular (pyrrole)N-H•••π(pyrrole) interactions in bis(2-pyrrolyl)methyl-ferrocene, an organometallic porphyrin precursor

被引：21

作者：

Gallagher, JF ^{[1
]}

Moriarty, E ^{[1
]}

机构：

[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199003625

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, C19H18FeN2 or [Fe(C5H5)(C14H13N2)], crystallizes in space group P2(1)/n with two molecules in the asymmetric unit. The pyrrole groups take part in intermolecular (pyrrole)N-H ...pi(pyrrole) interactions through a hydrogen-bonded ring system involving four pyrrole groups, with N ...(pyrrole centroid) distances in the range 3.209 (3)-3.427 (3) Angstrom and N-H ...(pyrrole centroid) angles in the range 127-139 degrees.

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页码：1079 / 1082

页数：4

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