Spinel Li1+xMn2O4 synthesized by coprecipitation as cathodes for lithium-ion batteries

被引:74
作者
Qiu, XP [1 ]
Sun, XG [1 ]
Shen, WC [1 ]
Chen, NP [1 ]
机构
[1] TSING HUA UNIV,DEPT MAT SCI & ENGN,BEIJING 100084,PEOPLES R CHINA
关键词
cathode; lithium-ion batteries; coprecipitation;
D O I
10.1016/S0167-2738(96)00540-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Spinel Li1+xMn2O4 was prepared by the coprecipitation of LiOH and Mn(OH)(2) in ethyl alcohol. The particle size is about 2 mu m with a narrow distribution. Cyclic voltammetry experiments using the Li/ethylene carbonate + dimethoxyethane + LiClO4/Li1+xMn2O4 cells show good reversibility of lithium deintercalation and intercalation in the spinel phase of Li1+xMn2O4. The initial reversible capacities are about 120 mA h/g and 140 mA h/g for x = 0 and x = 0.2, respectively.
引用
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页码:335 / 339
页数:5
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