A novel heterogeneous molecular catalyst for the Meerwein-Ponndorf-Verley and Oppenauer reactions

被引：38

作者：

Leyrit, P ^{[1
]}

McGill, C ^{[1
]}

Quignard, F ^{[1
]}

Choplin, A ^{[1
]}

机构：

[1] UNIV LYON 1,INST RECH CATALYSE,CNRS,F-69626 VILLEURBANNE,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 112卷 / 03期

关键词：

hydrogen transfer reduction; silica supported zirconium catalysts; alcohol oxidation; ketone reduction;

D O I：

10.1016/1381-1169(96)00234-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The silica anchored mononuclear (tris)isopropoxyzirconium, (=SiO)Zr(Oi-Pr)(3), is an efficient catalyst for the reduction of ketones and the oxidation of alcohols by hydrogen transfer. Easy separation of the products and recyclability of the catalyst are demonstrated.

引用

页码：395 / 400

页数：6

共 17 条

[1] Relative oxidation-reduction reactivities of ketones and aldehydes and applications in synthesis [J].

Adkins, H ;

Cox, FW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :1151-1159

[2] THE OXIDATION POTENTIALS OF ALDEHYDES AND KETONES [J].

ADKINS, H ;

ELOFSON, RM ;

ROSSOW, AG ;

ROBINSON, CC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (11) :3622-3629

[3] FROM CLUSTERS AND SURFACES TO CLUSTERS ON SURFACES - AN OPENING TOWARD SURFACE ORGANOMETALLIC CHEMISTRY [J].

BASSET, JM ;

CANDY, JP ;

CHOPLIN, A ;

NEDEZ, C ;

QUIGNARD, F ;

SANTINI, CC ;

THEOLIER, A .

MATERIALS CHEMISTRY AND PHYSICS, 1991, 29 (1-4) :5-32

[4]

CHOPLIN A, 1993, TRENDS INORG CHEM, V31, P463

[5]

Chuang IS, 1996, J AM CHEM SOC, V118, P401

[6]

Cox F.W., 1939, J. Am. Chem. Soc, V61, P3364

[7] SILYLMETHYL AND RELATED COMPLEXES .2. PREPARATION, SPECTRA, AND THERMOLYSIS OF TETRANEOPENTYLS OF TITANIUM, ZIRCONIUM, AND HAFNIUM [J].

DAVIDSON, PJ ;

LAPPERT, MF ;

PEARCE, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 57 (02) :269-277

[8] MEERWEIN-PONNDORF-VERLEY REDUCTIONS AND OPPENAUER OXIDATIONS - AN INTEGRATED APPROACH [J].

DEGRAAUW, CF ;

PETERS, JA ;

VANBEKKUM, H ;

HUSKENS, J .

SYNTHESIS-STUTTGART, 1994, (10) :1007-1017

[9] MEERWEIN-PONNDORF-VERLEY TYPE REDUCTION OF KETONES AND OPPENAUER TYPE OXIDATION OF ALCOHOLS UNDER THE INFLUENCE OF CP2ZRH2 [J].

ISHII, Y ;

NAKANO, T ;

INADA, A ;

KISHIGAMI, Y ;

SAKURAI, K ;

OGAWA, M .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (02) :240-242

[10]

IWASAWA Y, 1986, TAILORED MADE CATALY

← 1 2 →