Copper(II) sulfide?

被引：109

作者：

Goh, SW ^{[1
]}

Buckley, AN ^{[1
]}

Lamb, RN ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

来源：

MINERALS ENGINEERING | 2006年 / 19卷 / 02期

关键词：

sulphide ores; ore mineralogy; flotation activators; surface modification;

D O I：

10.1016/j.mineng.2005.09.003

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Reference to covellite as copper(II) sulfide has been challenged. To support the nominally Cu(I) formal oxidation state for covellite suggested by X-ray photoelectron spectroscopy, the Cu L-2,L-3 near-edge X-ray absorption fine structure spectrum for unoxidised covellite has been determined in fluorescence yield mode. Interpretation of the Cu L-3-edge spectrum has been effected with the assistance of ab initio calculations of the density of unfilled states and the simulation of spectra from both Cu sites in the covellite structure. An alternative explanation has been provided for a covellite Cu L-2,L-3-edge spectrum determined in electron yield mode that had been rationalised previously in terms of the presence of both Cu(I) and Cu(II) in the covellite structure. The relevance to mineral processing of the Cu(I) formal oxidation state in copper sulfides and other sulfide minerals has been discussed. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：204 / 208

页数：5

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