Generation of β-keto radicals from cyclopropanols catalyzed by AgNO3

被引：65

作者：

Chiba, S ^{[1
]}

Cao, ZY ^{[1
]}

El Bialy, SAA ^{[1
]}

Narasaka, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMISTRY LETTERS | 2006年 / 35卷 / 01期

关键词：

D O I：

10.1246/cl.2006.18

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various Beta-keto radicals are generated from cyclopropanols by treatment with a catalytic amount of AgNO3 and (NH4)(2)S2O8 as a reoxidant in the presence of pyridine. Thus, generated beta-keto radicals react with alkenes to yield addition products.

引用

页码：18 / 19

页数：2

共 16 条

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