Crystallization and X-ray structures of [NaYb(C5H5)(3)] and Yb(C5H5)(2)

被引：33

作者：

Apostolidis, C

Deacon, GB

Dornberger, E

Edelmann, FT

Kanellakopulos, B

MacKinnon, P

Stalke, D

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

[2] FORSCHUNGSZENTRUM KARLSRUHE,INST CHEM TECH,D-76021 KARLSRUHE,GERMANY

[3] OTTO VON GUERICKE UNIV,INST CHEM,D-39106 MAGDEBURG,GERMANY

[4] UNIV WURZBURG,INST ANORGAN CHEM,D-97074 WURZBURG,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 11期

关键词：

D O I：

10.1039/a700531h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex [NaYb(C5H5)(3)] (C5H5 = cyclopentadienyl), prepared from Yb(C5H5)(3) and sodium naphthalenide in tetrahydrofuran (thf) or from Yb(C5H5)(2) and Na(C5H5) in tetrahydrofuran and crystallized at ca, 400 degrees C (< 10(-4) mm Hg), is a three-dimensional polymer in which mu-eta(5):eta(5)-C5H5 groups link sodium and ytterbium (each metal having a pseudo-triangular arrangement of C5H5 ligands); Yb(C5H5)(2), similarly crystallized, has a polymeric chain structure with one terminal and two bridging C5H5 ligands per ytterbium, and there is eta(1)-bonding between adjacent chains.

引用

页码：1047 / 1048

页数：2

共 23 条

[1] STRUCTURE OF TRIS(ETA-5-CYCLOPENTADIENYL)YTTRIUM(III)
ADAM, M
BEHRENS, U
FISCHER, RD
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 968 - 971
[2] ADDUCTS OF CYCLOPENTADIENYL SODIUM AND METHYLCYCLOPENTADIENYL SODIUM WITH OXYGEN BASES AND NITROGEN BASES - STRUCTURE OF CYCLOPENTADIENYLSODIUMTETRAMETHYLETHYLENEDIAMINE, NA(C5H5)(ME2NCH2CH2NME2)
AOYAGI, T
SHEARER, HMM
WADE, K
WHITEHEAD, G
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 175 (01) : 21 - 31
[3] DICYCLOPENTADIENYLSAMARIUM COMPLEXES WITH TERT-BUTYL SUBSTITUENTS IN THE RING - CRYSTAL AND MOLECULAR-STRUCTURES OF THE SOLVATE (ETA-5-C5H3BUT2)2SM . OC4H8 AND HOMOLEPTIC ATE COMPLEX [NASM(ETA-5-ETA-2-C5H4BUT)3 . OC4H8]N
BELSKY, VK
GUNKO, YK
BULYCHEV, BM
SIZOV, AI
SOLOVEICHIK, GL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 390 (01) : 35 - 44
[4] ORGANOLANTHANOIDS .9. ELECTROCHEMICAL REDUCTION OF TRIS(CYCLOPENTADIENYL)SAMARIUM(III), TRIS(CYCLOPENTADIENYL)YTTERBIUM(III), AND TRIS(CYCLOPENTADIENYL)EUROPIUM(III) COMPOUNDS IN TETRAHYDROFURAN
BOND, AM
DEACON, GB
NEWNHAM, RH
[J]. ORGANOMETALLICS, 1986, 5 (11) : 2312 - 2316
[5] PREPARATION OF THE 1ST MOLECULAR ETA-2-ACETYLENE COMPLEX OF A 4F TRANSITION-METAL, (ME5C5)2YB(ETA-2-MEC=CME)
BURNS, CJ
ANDERSEN, RA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (03) : 941 - 942
[6] BURNS CJ, 1987, THESIS U CALIFORNIA
[7] CYCLOPENTADIENIDES OF YTTERBIUM (3) AND YTTERBIUM (2)
CALDERAZZO, F
PAPPALARDO, R
LOSI, S
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1966, 28 (04): : 987 - +
[8] REINVESTIGATION OF A TRANSMETALLATION SYNTHESIS OF BIS(CYCLOPENTADIENYL)SAMARIUM(II) AND FORMATION OF A NEW SOLUBLE CYCLOPENTADIENYLSAMARIUM(II) COMPOUND
DEACON, GB
PAIN, GN
TUONG, TD
[J]. POLYHEDRON, 1985, 4 (06) : 1149 - 1150
[9] ORGANOLANTHANOIDS .6. SYNTHESES OF CYCLOPENTADIENYLLANTHANOIDS BY TRANSMETALLATION REACTIONS BETWEEN THALLOUS CYCLOPENTADIENIDES AND LANTHANOID ELEMENTS
DEACON, GB
KOPLICK, AJ
TUONG, TD
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (03) : 517 - 525
[10] Edelman F, 1995, COMPREHENSIVE ORGA 2, V4, P11

← 1 2 3 →