A Stable "End-On" Iron(III)-Hydroperoxo Complex in Water Derived from a Multi-Iron(II)-Substituted Polyoxometalate and Molecular Oxygen

被引：39

作者：

Barats, Delina ^{[1
]}

Leitus, Gregory ^{[2
]}

Popovitz-Biro, Ronit ^{[2
]}

Shimon, Linda J. W. ^{[2
]}

Neumann, Ronny ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

[2] Weizmann Inst Sci, Chem Res Support Unit, IL-76100 Rehovot, Israel

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 51期

基金：

以色列科学基金会;

关键词：

iron; O-O activation; oxygen; peroxo ligands; polyoxometalates;

D O I：

10.1002/anie.200803966

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure presented) Head over EELS: Reaction of O2 with a hexa-iron(II)-substituted polyoxometalate in water yields a polyoxometalate with "end-on" hydroperoxo groups, {FeIII-O2H}, at the terminal positions. The hydroperoxo moiety, stabilized by hydrogen bonding with water, is unusual for its long O-O bond and nearly linear Fe-O-O bond angle. Electron energy-loss spectroscopy (EELS) is used to determine the oxidation state of iron. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9908 / 9912

页数：5

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