Far infrared transmittance of Sc-2@C-84 and Er-2@C-82

被引:19
作者
Grannan, SM
Birmingham, JT
Richards, PL
Bethune, DS
deVries, MS
vanLoosdrecht, PHM
Dorn, HC
Burbank, P
Bailey, J
Stevenson, S
机构
[1] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,DIV MAT SCI,BERKELEY,CA 94720
[2] IBM CORP,DIV RES,ALMADEN RES CTR,SAN JOSE,CA 95120
[3] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061
关键词
D O I
10.1016/S0009-2614(96)01313-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have measured the far infrared transmittance of Sc-2@C-84 and Er-2@C-82 at 1.5 K between 30 and 200 cm(-1). Both materials are observed to have a large primary absorption feature centered at 95 cm(-1) with a width of approximately 50 cm(-1), as well as a number of secondary absorption features which are different in the two materials, This is the first study of the far infrared properties of metallofullerenes and may help in the determination of the structural and electronic properties of these materials.
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收藏
页码:359 / 365
页数:7
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