Solubility of flouranthene, chrysene, and triphenylene in supercritical carbon dioxide

被引：42

作者：

Barna, L ^{[1
]}

Blanchard, JM ^{[1
]}

Rauzy, E ^{[1
]}

Berro, C ^{[1
]}

机构：

[1] FAC SCI LUMINY, CHIM PHYS LAB, F-13288 MARSEILLE 9, FRANCE

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1996年 / 41卷 / 06期

关键词：

D O I：

10.1021/je960189n

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The solubility of polycyclic aromatic hydrocarbons in supercritical carbon dioxide is very low, and very little experimental data exist. A method has been developed for the measurement of such low solubilities, and the solubilities of fluoranthene, chrysene, and triphenylene in a temperature range 308.15 K to 328.15 K and in a pressure range 84 bar to 251 bar have been determined. The solubilities have been fitted to the excess function-equation of state model.

引用

页码：1466 / 1469

页数：4

共 11 条

[1] AN EXCESS FUNCTION-EQUATION OF STATE MODEL FOR SOLUBILITY OF HYDROCARBON SOLIDS IN SUPERCRITICAL CARBON-DIOXIDE [J].

BARNA, LR ;

RAUZY, E ;

BERRO, C ;

BLANCHARD, JM .

FLUID PHASE EQUILIBRIA, 1994, 100 :191-208

[2] SOLUBILITIES OF SOLIDS AND LIQUIDS OF LOW VOLATILITY IN SUPERCRITICAL CARBON-DIOXIDE [J].

BARTLE, KD ;

CLIFFORD, AA ;

JAFAR, SA ;

SHILSTONE, GF .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1991, 20 (04) :713-756

[3] A group-contribution equation of state for predicting vapor-liquid equilibria and volumetric properties of carbon dioxide-hydrocarbons systems [J].

Berro, C ;

Barna, L ;

Rauzy, E .

FLUID PHASE EQUILIBRIA, 1996, 114 (1-2) :63-87

[4] REPRESENTATION AND PREDICTION OF THERMOPHYSICAL PROPERTIES OF HEAVY HYDROCARBONS [J].

CONIGLIO, L ;

RAUZY, E ;

BERRO, C .

FLUID PHASE EQUILIBRIA, 1993, 87 (01) :53-88

[5] HIGH-PRESSURE FLUID-PHASE EQUILIBRIA - EXPERIMENTAL METHODS AND SYSTEMS INVESTIGATED (1988-1993) [J].

DOHRN, R ;

BRUNNER, G .

FLUID PHASE EQUILIBRIA, 1995, 106 (1-2) :213-282

[6]

HOYER H, 1958, Z ELEKTROCHEM, V62, P61

[7] SOLUBILITIES OF HYDROCARBON SOLIDS IN SUPERCRITICAL FLUIDS - THE AUGMENTED VANDERWAALS TREATMENT [J].

JOHNSTON, KP ;

ZIGER, DH ;

ECKERT, CA .

INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1982, 21 (03) :191-197

[8] SOLUBILITY OF SOLIDS IN SUPERCRITICAL CARBON-DIOXIDE AND ETHYLENE [J].

KURNIK, RT ;

HOLLA, SJ ;

REID, RC .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1981, 26 (01) :47-51

[9] SOLID SOLUBILITIES OF NAPHTHALENE AND BIPHENYL IN SUPERCRITICAL CARBON-DIOXIDE [J].

MCHUGH, M ;

PAULAITIS, ME .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1980, 25 (04) :326-329

[10]

Paulaitis M. E., 1983, Rev. Chem. Eng, V1, P179, DOI [10.1016/8978-0-12-409547-2.10753.X, DOI 10.1016/B978-0-12-409547-2.10753-X]

← 1 2 →