Tetrahedral bipyridyl copper(I) complexes: a new class of non-dipolar chromophore for nonlinear optics

被引：66

作者：

Renouard, T

Le Bozec, H

Brasselet, S

Ledoux, I

Zyss, J

机构：

[1] Univ Rennes 1, Lab Chim Coordinat & Catalyse, CNRS, UMR 6509, F-35042 Rennes, France

[2] ENS Cachan, Lab Photon Quant & Mol, F-94235 Cachan, France

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 10期

关键词：

D O I：

10.1039/a901972c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of 4,4'-bis(dialkylaminostyryl)-6,6'-dimethyl-2,2'-bipyridine ligands is described; the corresponding tetrahedral bis(bipyridyl) copper(I) complexes have been prepared, and their second-order nonlinear optical properties determined by harmonic light scattering (HLS) at 1.34 mu m; these new octupolar complexes exhibit large molecular hyperpolarisabilities beta.

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页码：871 / 872

页数：2

相关论文

共 27 条

[1]

Baum G, 1999, CHEM COMMUN, P195

[2]

BLANCHARDDESCE M, 1997, OPT MATER, V6, P276

[3] Synthesis and characterization of 4-alkenyl and 4,4'-dialkenyl-2,2'-bipyridyl ligands bearing pi-donor substituents [J].

Bourgault, M ;

Renouard, T ;

Lognone, B ;

Mountassir, C ;

LeBozec, H .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1997, 75 (03) :318-325

[4] ON THE 2ND-ORDER POLARIZABILITY OF CONJUGATED PI-ELECTRON MOLECULES WITH OCTUPOLAR SYMMETRY - THE CASE OF TRIAMINOTRINITROBENZENE [J].

BREDAS, JL ;

MEYERS, F ;

PIERCE, BM ;

ZYSS, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (12) :4928-4929

[5] CRYSTAL AND MOLECULAR-STRUCTURES OF BIS(4,4',6,6'-TETRAMETHYL-2,2'-BIPYRIDYL)COPPER(I) PERCHLORATE, BIS(4,4',6,6'-TETRAMETHYL-2,2'-BIPYRIDYL)COPPER(II) DIPERCHLORATE, AND BIS(4,4',6,6'-TETRAMETHYL-2,2'-BIPYRIDYL)COPPER(II) DIPERCHLORATE DIHYDRATE - A SEARCH FOR COPPER(II) AND COPPER(I) COMPLEXES WITH A COMMON LIGAND ENVIRONMENTHL [J].

BURKE, PJ ;

HENRICK, K ;

MCMILLIN, DR .

INORGANIC CHEMISTRY, 1982, 21 (05) :1881-1886

[6] CHIRAL METAL-COMPLEXES WITH LARGE OCTUPOLAR OPTICAL NONLINEARITIES [J].

DHENAUT, C ;

LEDOUX, I ;

SAMUEL, IDW ;

ZYSS, J ;

BOURGAULT, M ;

LEBOZEC, H .

NATURE, 1995, 374 (6520) :339-342

[7] INTERLOCKING OF MOLECULAR THREADS - FROM THE STATISTICAL APPROACH TO THE TEMPLATED SYNTHESIS OF CATENANDS [J].

DIETRICHBUCHECKER, CO ;

SAUVAGE, JP .

CHEMICAL REVIEWS, 1987, 87 (04) :795-810

[8] HIGH-YIELD SYNTHESIS OF A DICOPPER(I) TREFOIL KNOT CONTAINING 1,3-PHENYLENE GROUPS AS BRIDGES BETWEEN THE CHELATE UNITS [J].

DIETRICHBUCHECKER, CO ;

SAUVAGE, JP ;

DECIAN, A ;

FISCHER, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (19) :2231-2232

[9] DICOPPER(I) TREFOIL KNOTS AND RELATED UNKNOTTED MOLECULAR-SYSTEMS - INFLUENCE OF RING SIZE AND STRUCTURAL FACTORS ON THEIR SYNTHESIS AND ELECTROCHEMICAL AND EXCITED-STATE PROPERTIES [J].

DIETRICHBUCHECKER, CO ;

NIERENGARTEN, JF ;

SAUVAGE, JP ;

ARMAROLI, N ;

BALZANI, V ;

DECOLA, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (24) :11237-11244

[10] 2ND-ORDER OPTICAL NONLINEARITY IN OCTUPOLAR AROMATIC SYSTEMS [J].

JOFFRE, M ;

YARON, D ;

SILBEY, RJ ;

ZYSS, J .

JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (08) :5607-5615