Mono- and dinuclear copper(I) complexes with methyl-substituted pyrimidinethiones

被引：14

作者：

Falcomer, VAS

Lemos, SS ^{[1
]}

Batista, AA

Ellena, J

Castellano, EE

机构：

[1] Univ Brasilia, Inst Quim, BR-70904970 Brasilia, DF, Brazil

[2] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil

[3] Univ Sao Paulo, Inst Fis, BR-13560970 Sao Carlos, SP, Brazil

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 04期

关键词：

methyl-substituted pyrimidinethiones; mono- and dinuclear copper(I) complexes; copper(I)-hydrogen interactions; X-ray crystal structure; model complexes;

D O I：

10.1016/j.ica.2005.11.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

The reaction of 4,6-dimethylpyrimidine-2(1H)-thione (dmpymtH) or its corresponding N-methylated form (dmpymt-NMe) with the parent complex [Cu(MeCN)(4)][BF4] (1) affords the mono- and dinuclear copper(I) complexes [Cu(dmpymt-NMe)(3)][BF4] (2) and [Cu(dmpymtH)(3)](2)[BF4]2 (center dot) 2H(2)O (3), respectively. The reaction Of Cu2O and the hydrochloride salt of dmpymtH gives the dinuclear complex [CuCl(dmpymtH)(2)](2) (4). The X-ray crystal structure reveals that 2 is coordinatively unsaturated and weak intermolecular interactions between Cu(I) and H atoms from methyl groups are involved. The complexes 3 and 4 are dinuclear in the solid state in which the copper atoms adopt distorted tetrahedral geometry. In both cases, the neutral dmpymtH is acting as a bridging ligand. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1064 / 1070

页数：7

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