Detailed tephrochronological studies in Kamchatka Peninsula, Russia, permitted documentation of 24 Holocene key-marker tephra layers related to the largest explosive eruptions from 11 volcanic centers. Each layer was traced for tens to hundreds of kilometers away from the source volcano; its stratigraphic position, area of dispersal, age, characteristic features of grain-size distribution, and chemical and mineral composition confirmed its identification, The most important marker tephra horizons covering a large part of the peninsula are (from north to south; ages given in C-14 yr B.P.) SH2 (approximate to 1000 yr B.P.) and SH3 (approximate to 1400 yr B.P.) from Shiveluch volcano; KZ (approximate to 7500 yr B.P.) from Kizimen volcano; KRM (approximate to 7900 yr B.P.) from Karymsky caldera; KHG (approximate to 7000 yr B.P.) from Khangar volcano; AV(1) (approximate to 3500 yr B.P.), AV(2) (approximate to 4000 yr B.P.), AV(4) (approximate to 5500 yr B.P.), and AV(5) (approximate to 5600 yr B.P.) from Avachinsky volcano; OP (approximate to 1500 yr B.P.) from the Baraniy Amfiteatr crater at Opala volcano; KHD (approximate to 2800 yr B.P.) from the ''maar'' at Khodutka volcano; KS1 (approximate to 1800 yr B.P.) and KS2 (approximate to 6000 yr B.P.) from the Ksudach calderas; KSht(3) (A.D. 1907) from Shtyubel cone in Ksudach volcanic massif; and KO (approximate to 7700 yr B.P.) from the Kuril Lake-Iliinsky caldera. Tephra layers SH5 (approximate to 2600 yr B.P.) from Shiveluch volcano, AV(3) (approximate to 4500 yr B.P.) from Avachinsky volcano, OPtr (approximate to 4600 yr B.P.) from Opala volcano, KS3 (approximate to 6100 yr B.P.) and KS4 (approximate to 8800 yr B.P.) from Ksudach calderas, KSht(1) (approximate to 1100 yr B.P.) from Shtyubel cone, and ZLT (approximate to 4600 yr B.P.) from Iliinsky volcano cover smaller areas and have local stratigraphic value, as do the ash layers from the historically recorded eruptions of Shiveluch (SH1964) and Bezymianny (B-1956) volcanoes. The dated tephra layers provide a record of the most voluminous explosive events in Kamchatka during the Holocene and form a tephrochronological timescale for dating and correlating various deposits. (C) 1997 University of Washington.