Mechanistically significant details of the H/D exchange reactions of propene over acidic zeolite catalysts

被引：31

作者：

Marcus, DM ^{[1
]}

Hayman, MJ ^{[1
]}

Blau, YM ^{[1
]}

Guenther, DR ^{[1
]}

Ehresmann, JO ^{[1
]}

Kletnieks, PW ^{[1
]}

Haw, JF ^{[1
]}

机构：

[1] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 12期

关键词：

heterogeneous catalysis; isotopic labeling; microporous materials; oligonnerization; zeolites;

D O I：

10.1002/anie.200503471

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quid pro quo: Hydrogen-deuterium exchange of propene on solid acid catalysts was studied at 573 and 673 K with a reaction time of 3 s (see scheme). At low partial pressures and temperatures, H/D exchange produced [D 5]propene as the main product. Complete deuteration ([D 6]propene) was observed only at a higher temperature with the most acidic catalyst. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1933 / 1935

页数：3

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