Novel synthetic route to soluble polyanions:: synthesis and crystal structure of [K(18-crown-6)]4[Pb9]•en•tol

被引：28

作者：

Fässler, TF ^{[1
]}

Hoffmann, R ^{[1
]}

机构：

[1] ETH Zurich, Anorgan Chem Lab, CH-8092 Zurich, Switzerland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 19期

关键词：

D O I：

10.1039/a906586e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[K(18-crown-6)](4)[Pb-9] was obtained by a novel synthetic procedure, which allows the generation of polyanions by direct reduction of the elements in molten crown ethers at temperatures slightly above 40 degrees C; the crystal structure refinement shows the coordination of three K atoms to the nonaplumbide anion.

引用

页码：3339 / 3340

页数：2

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