Synthesis and structure of a two-dimensional vanadium tellurite, [H2en][VTeO5]2

被引：10

作者：

Jung, Kyungna

Kim, Hyejin

Yun, Hoseop

Do, Junghwan ^{[1
]}

机构：

[1] Konkuk Univ, Dept Chem, Seoul 143701, South Korea

[2] Konkuk Univ, Res Ctr Organ Display, Seoul 143701, South Korea

[3] Ajou Univ, Dept Chem, Suwon, South Korea

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2006年 / 632卷 / 8-9期

关键词：

vanadium; tellurium; hydrothermal reaction; vanadium tellurite; templates;

D O I：

10.1002/zaac.200600066

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[H(2)en][VTeO5](2) (en = ethylenediamine) was synthesized by a hydrothermal reaction and structurally charac terized. The structure of [H(2)en][VTeO5](2) consists of an infinite [VTeO5](-) layer, which contains VO4 tetrahedral and TeO5 square pyramidal units. Two square pyramidal TeO5 units are connected by sharing an edge to form a Te2O8 binuclear unit. The interlayer space is filled by diprotonated ethylenediammonium cations that link the layers through a network of hydrogen bonds.

引用

页码：1582 / 1585

页数：4

共 24 条

[1] COMPOUND FORMATION IN THE SYSTEMS TEO2-SEO2 AND TEO2-SEO2-H2O [J].